海洋调查与观测

基于聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解无机碳电极及其性能标定

  • 韩沉花 ,
  • 潘依雯 ,
  • 叶瑛
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  • 浙江大学海洋科学与工程学系,浙江 杭州 310027

收稿日期: 2008-11-15

  修回日期: 2009-03-02

  网络出版日期: 2010-02-05

摘要

深海探测溶解无机碳含量异常,可以为寻找热液口提供一个很好的证据。本文设计的基于自制的聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解无机碳探测电极属于电势型电极,适用于对深海中溶解无机碳的测量,具有体积微小、便于与pH、盐度、温度、氧化还原电位等多种传感器集成在同一探头腔内,实施在线探测等优点。实验室条件下,将该溶解无机碳探测电极与银/氯化银参比电极分别接在Keithley 6517A高阻抗电位计输入端进行测试,测试结果表明:该电极对不同浓度的碳酸氢钠溶液具有良好的响应信号,响应时间大约在30s—1 min,检测限在10-1—10-4mol?L–1。

本文引用格式

韩沉花 , 潘依雯 , 叶瑛 . 基于聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解无机碳电极及其性能标定[J]. 热带海洋学报, 2009 , 28(4) : 35 -41 . DOI: 10.11978/j.issn.1009-5470.2009.04.035

Abstract

A good method to find hydrothermal vents is to detect the abnormal concentration of dissolved inorganic carbon in deep ocean. The authors have designed a dissolved inorganic carbon microelectrode based on polydimethylsiloxane(PDMS)gel and Zinc-Aluminium-hydrotalcite (Zn-Al-LDH) ion carrier complex membrane, which can be used to detect deep-ocean inorganic carbon abnormality. This dissolved inorganic carbon microelectrode is miniature, and can conveniently be integrated in the same probing cavity with pH microelectrode, salinity meter, temperature sensor, oxidation-reduction potential sensor, etc. to detect various in-situ signals. It has been tested in the laboratory condition, together with Ag/AgCl reference microelectrode, connecting with the input of Keithley 6517A high-resistant potentiometer. It was shown that the signals responded well to different concentrations of NaHCO3 solutions, with 30-60 second c.a. response time and a limiting range between 10-1 and 10-4 mol?L–1.
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